Tetrahedron letters

The reaction of tris (trimethylsilyl) silane with acid chlorides

M Ballestri, C Chatgilialoglu, N Cardi, A Sommazzi

Index: Ballestri; Chatgilialoglu; Cardi; Sommazzi Tetrahedron Letters, 1992 , vol. 33, # 13 p. 1787 - 1790

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Citation Number: 35

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Tris(trimethylsilyl)silane, in contrast with tributylin hydridge, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. ... Tris(trimethysilyl)silane reduces acid ...

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