Catalytic hydrogenation reactions by a monobenzene complex of ruthenium,[Ru (η6-C6H6)(CH3CN) 3](BF4) 2, in biphasic medium

C Wai-Chung, L Chak-Po, L Cheng…

Index: Chan, Wai-Chung; Lau, Chak-Po; Cheng, Lin; Leung, Yin-Shan Journal of Organometallic Chemistry, 1994 , vol. 464, # 1 p. 103 - 106

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Abstract

Abstract The water soluble monobenzene complex of ruthenium,[Ru (η 6-C 6 H 6)(CH 3 CN) 3](BF 4) 2 (1) is an effective catalyst or catalyst precursor for the hydrogenation of olefinic functions in benzene/H 2 O biphasic medium. The catalyst can be recycled by simple decantation. Complex 1 is capable of catalyzing H/D exchange reaction between H 2 and D 2 O. A two-loop reaction mechanism for the catalytic hydrogenation reactions with 1 is ...

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