Bicyclo [3.2. 2] non-1-ene: matrix isolation and spectroscopic characterization of a moderately strained bridgehead olefin

…, JG Radziszewski, P Kaszynski, J Michl

Index: Gudipati, Murthy S.; Radziszewski, Juliusz G.; Kaszynski, Piotr; Michl, Josef Journal of Organic Chemistry, 1993 , vol. 58, # 14 p. 3668 - 3674

Full Text: HTML

Citation Number: 10

Abstract

Bicycle [3.2. 2111011-1-ene was generated in low-temperature matrices and in fluid solutions by photodecomposition of bicyclo [2.2. 2loct-l-yldiazomethane and its photorearrangement product, 3-(bicyclo [2.2. 2loct-l-yl) diazirine. It was characterized by IR and UV absorption and by lH and l3C NMR spectroscopy. Further evidence for the proposed structure was provided by self-trapping and by the spectral effects of deuteration on the ...