A Reinvestigation of the Trimethylstannylation of 1-Iodonorbornane: Competition between Polar and Radical Pathways
W Adcock, CI Clark
Index: Adcock, William; Clark, Christopher I. Journal of Organic Chemistry, 1995 , vol. 60, # 3 p. 723 - 724
Full Text: HTML
Citation Number: 15
Abstract
1 2 3 exclusively via an SRNl free radical pathway, l-iodonorbornane (1; X= I, Y= H) reacts by competing free radical and halogen-metal exchange (HME) pathways. l This proposal was based largely on product distribution results (substitution versus reduction) in the absence and presence of tert-butylamine (TBA) and, as well, the detailed results of trimethylstannylation of 1, 4-dihalobicyclo [2.2. 11-heptanes (1) l and 1, 4-dihalobicyclo [ ...
Related Articles:
[Neuman, Robert C.; Berge, Charles T.; Binegar, Glen Al.; Adam, Waldemar; Nishizawa, Yoshinori Journal of Organic Chemistry, 1990 , vol. 55, # 15 p. 4564 - 4568]
[Greer, Melinda L.; Sarker, Haripada; Mendicino, Maria E.; Blackstock, Silas C. Journal of the American Chemical Society, 1995 , vol. 117, # 42 p. 10460 - 10467]
[Fossey, Jacques; Lefort, Daniel Tetrahedron, 1980 , vol. 36, # 81 p. 1023 - 1036]
[Gudipati, Murthy S.; Radziszewski, Juliusz G.; Kaszynski, Piotr; Michl, Josef Journal of Organic Chemistry, 1993 , vol. 58, # 14 p. 3668 - 3674]
[Gudipati, Murthy S.; Radziszewski, Juliusz G.; Kaszynski, Piotr; Michl, Josef Journal of Organic Chemistry, 1993 , vol. 58, # 14 p. 3668 - 3674]