The Hydrolysis and Oxidation of α, ι-Bis (methylthio) polyfluoroalkanes
RB Ward
Index: Ward,R.B. Journal of Organic Chemistry, 1965 , vol. 30, p. 3009 - 3011
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Citation Number: 10
Abstract
Treatment of 1, 6-bis (methylthio) dodecafluorohexane with concentrated sulfuric acid at temperatures of 150-180" in Hastelloy B pressure equipment causes hydrolysis of the terminal difluoromethylene groups, removal of the sulfur function, and formation of octafluorohexanedioic acid, isolated as the dimethyl ester. Similarly, the dimethyl esters of tetrafluorosuccinic, dodecafluorooctanedioic, and hexadecafluorodecanedioic acids were ...
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