Investigations on the kinetics of hydroformylation of 1-hexene using HRh (CO)(PPh 3) 3 encapsulated hexagonal mesoporous silica as a heterogeneous catalyst

N Sudheesh, SK Sharma, RS Shukla…

Index: Sudheesh; Sharma, Sumeet K.; Shukla, Ram S.; Jasra, Raksh V. Journal of Molecular Catalysis A: Chemical, 2010 , vol. 316, # 1-2 p. 23 - 29

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Citation Number: 16

Abstract

Kinetics of HRh (CO)(PPh3) 3 encapsulated in hexagonal mesoporous silica has been investigated for the heterogeneous catalyzed hydroformylation of 1-hexene. The rates of hydroformylation of C5–C12 alkenes, determined under identical conditions, indicated a decreasing trend on increasing the chain length of the alkenes. The representative alkene, 1- hexene has been subjected for detail kinetic investigations. The 1-hexene ...

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