Applied Organometallic Chemistry

Highly efficient catalytic system for electrophilic amination of arylzinc reagents

T Daşkapan, S Koca

Index: Daskapan, Tahir; Koca, Selcuk Applied Organometallic Chemistry, 2010 , vol. 24, # 1 p. 12 - 16

Full Text: HTML

Citation Number: 4

Abstract

Abstract The effect of catalyst on the yield of amine in the amination of three classes of arylzinc reagents with acetone oxime O-tosylate was investigated. Since they allowed the preparation of arylamines in excellent yields in the presence of a minimum amount of copper (I) or copper (II) compounds, the catalytic systems using copper (I) or copper (II) combined with a P-, N-or S-donor ligand were revealed to be the best catalysts for the electrophilic ...

Related Articles:

Easy Copper??Catalyzed Synthesis of Primary Aromatic Amines by Couplings Aromatic Boronic Acids with Aqueous Ammonia at Room Temperature

[Rao, Honghua; Fu, Hua; Jiang, Yuyang; Zhao, Yufen Angewandte Chemie - International Edition, 2009 , vol. 48, # 6 p. 1114 - 1116]

Metal-free C–N bond-forming reaction: straightforward synthesis of anilines, through cleavage of aryl C–O bond and amide C–N bond

[Yu, Jianzhong; Zhang, Peizhi; Wu, Jun; Shang, Zhicai Tetrahedron Letters, 2013 , vol. 54, # 24 p. 3167 - 3170]

Base-mediated rearrangement of free aromatic hydroxamic acids (ArCO–NHOH) to anilines

[Hoshino, Yujiro; Okuno, Moriaki; Kawamura, Eri; Honda, Kiyoshi; Inoue, Seiichi Chemical Communications, 2009 , # 17 p. 2281 - 2283]

Highly Selective Amination of o-and p-Alkyl Phenols over Pd/Al 2 O 3-BaO

[Ma, Jianchao; Wang, Huabang; Sun, Meng; Yang, Fan; Wu, Zhiwei; Wang, Donghua; Chen, Ligong Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 2 p. 387 - 392]

Iron and ruthenium carbonyl catalyzed reductive carbonylation of nitro compounds by sodium methoxide. A significant effect of the metal on the reaction course

[Journal of the American Chemical Society, , vol. 103, # 21 p. 6514 - 6515]

More Articles...