Easy Copper??Catalyzed Synthesis of Primary Aromatic Amines by Couplings Aromatic Boronic Acids with Aqueous Ammonia at Room Temperature

H Rao, H Fu, Y Jiang, Y Zhao

Index: Rao, Honghua; Fu, Hua; Jiang, Yuyang; Zhao, Yufen Angewandte Chemie - International Edition, 2009 , vol. 48, # 6 p. 1114 - 1116

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Citation Number: 125

Abstract

Primary aromatic amines are widely used in the synthesis of natural products, pharmaceutical and medicinal compounds, as well as polymers and materials,[1] and their preparation has attracted increasing attention. Ammonia is an abundant and inexpensive chemical reagent, so it is an attractive amino source in organic synthesis.[2] Traditional synthesis of primary amines has been performed through couplings of aryl halides with ...

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