Microwave-assisted synthesis of symmetrical and unsymmetrical N, N′-disubstituted thioureas and ureas over MgO in dry media
H Valizadeh, L Dinparast
Index: Valizadeh, Hassan; Dinparast, Leila Monatshefte fur Chemie, 2012 , vol. 143, # 2 p. 251 - 254
Full Text: HTML
Citation Number: 3
Abstract
Abstract Under mild microwave irradiation conditions a variety of symmetrical and unsymmetrical N, N′-disubstituted thioureas and ureas were prepared via the reaction of N- monosubstituted hydroxylamines with isocyanate and isothiocyanate derivatives over MgO under solvent-free conditions. This new method afforded satisfactory results with good yields, short reaction time, and simplicity in the experimental procedure. Graphical abstract
Related Articles:
Conformational preferences in alkylnitrosoureas
[Snyder, John K.; Stock, Leon M. Journal of Organic Chemistry, 1980 , vol. 45, # 5 p. 886 - 891]
[Schweim, Harald G. Archiv der Pharmazie (Weinheim, Germany), 1987 , vol. 320, # 5 p. 430 - 437]
[Kniphorst Recueil des Travaux Chimiques des Pays-Bas, 1925 , vol. 44, p. 704]
[Schweim, Harald G. Archiv der Pharmazie (Weinheim, Germany), 1987 , vol. 320, # 5 p. 430 - 437]
[Koyano,K.; McArthur,C.R. Canadian Journal of Chemistry, 1973 , vol. 51, p. 333 - 337]