The Journal of Organic Chemistry

Conformational preferences in alkylnitrosoureas

JK Snyder, LM Stock

Index: Snyder, John K.; Stock, Leon M. Journal of Organic Chemistry, 1980 , vol. 45, # 5 p. 886 - 891

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Citation Number: 33

Abstract

The spectroscopic properties of several N-alkyl-N-nitrosoureas, N, N'-dialkyl-N-nitrosoureas, and N, N', N'-trialkyl-N-nitrosoureas have been studied in carbon disulfide and chloroform solutions. The NH stretching frequencies in the IR spectra have been observed in both concentrated and dilute solution and in the presence of added dioxane. The results indicate that there is a strong intramolecular hydrogen bond in the mono-and dialkylnitrosoureas. ...