The Journal of Organic Chemistry

Reactions of acyl thiochlorosulfites

S Motoki, H Kagami

Index: Motoki,S.; Kagami,H. Journal of Organic Chemistry, 1976 , vol. 41, p. 2759 - 2762

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Abstract

Dialkylammonium dialkyldithiocarbamates reacted with lb at-30 “C to give an oily product. The ir of the oil (VC= O 1690 cm-l, US-0 1150 cm-l) appeared in a different region from those of lb and the spectra of the fingerprint region resembled closely that of dithiocarbamates. So the product was assumed to be acylthiocarbamoyl dithiosulfites (5). This product was unstable and gradually decomposed at room temperature to give N-dialkyl-p- ...

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