Pd??Catalyzed Reaction of Allyl Carbonate with Polyols: The Role of CO2 in Transesterification versus Etherification of Glycerol
A Gordillo, GC Lloyd??Jones
Index: Gordillo, Alvaro; Lloyd-Jones, Guy C. Chemistry - A European Journal, 2012 , vol. 18, # 9 p. 2660 - 2665
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Citation Number: 7
Abstract
Abstract An intermolecular Pd/PPh 3-catalyzed transesterification of diallyl carbonate with glycerol to generate glycerol carbonate has been developed. Analysis of the reaction kinetics in THF indicates a first-order dependence on Pd and diallyl carbonate, that the Pd
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