Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 …
HA Ferguson, JD Ferguson…
Index: Ferguson, Heather A.; Ferguson, John D.; Holmes, Bert E. Journal of Physical Chemistry A, 1998 , vol. 102, # 28 p. 5393 - 5397
Full Text: HTML
Citation Number: 12
Abstract
Chemically activated CF3CH2CF3 was prepared with 104 kcal/mol of internal energy by the combination of CF3CH2 and CF3 radicals, and chemically activated CF3CH2CH3 was prepared with 101 and 95 kcal/mol by combination of CF3 and CH2CH3 radicals and by combination of CF3CH2 and CH3 radicals, respectively. The experimental rate constants for unimolecular 1, 2-dehydrofluorination were 1.2× 105 s-1 for CF3CH2CF3 and 3.2× 106 s- ...
Related Articles:
Estimation of hydrocarbon solubilities in hydrofluorocarbons
[Puy, Michael Van Der; Poss, Andrew J.; Persichini, Phillip J.; Ellis, Lois A. S. Journal of Fluorine Chemistry, 1994 , vol. 67, # 3 p. 215 - 224]
The Chemistry of Sulfur Tetrafluoride. II. The Fluorination of Organic Carbonyl Compounds1
[Hasek,W.R. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 543 - 551]
Synthesis and tritium-induced F NMR shifts of 1, 1, 1, 4, 4, 4-hexafluoro-2, 3 ditritio-2-butene
[Angelini, G.; Lilla, G.; Sparapani, C.; Ursini, O.; Rossi, E.; et al. Canadian Journal of Chemistry, 1992 , vol. 70, # 4 p. 1221 - 1228]
One step synthesis of 1, 1, 1, 4, 4, 4-hexafluorobutane from succinonitrile
[Baker, Max T.; Ruzicka, Jan A.; Tinker, John H. Journal of Fluorine Chemistry, 1999 , vol. 94, # 2 p. 123 - 126]
[Bordwell, F. G.; Wilson, Craig A. Journal of the American Chemical Society, 1987 , vol. 109, # 18 p. 5470 - 5474]