Reactions of Polyhaloparaffins with Grignard Reagents. 1, 1, 1-Trichloropentane

CR Kinney, WL Spliethoff

Index: Kinney; Spliethoff Journal of the American Chemical Society, 1949 , vol. 71, p. 747

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Abstract

A well known and convenient method for preparing small amounts of boron trichloride or boron tribromide comprises passing boron trifluoride gas over aluminum chloride or aluminum bromide.'I recently have found that a reaction may occur at elevated temperatures between aluminum chloride and boric oxide to produce boron trichloride.