Tetrahedron letters

A one step synthesis of 1, 4-benzodiazepines: synthetic studies on neothramycin

M Mori, M Kimura, Y Uozumi, Y Ban

Index: Mori, Miwako; Kimura, Masaya; Uozumi, Yasuhiro; Ban, Yoshio Tetrahedron Letters, 1985 , vol. 26, # 48 p. 5947 - 5950

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Citation Number: 33

Abstract

Abstract A one step synthesis of 1, 4-benzodiazepines from o-haloanilines and amino acids was achieved by use of palladium catalyzed carbonylation, by which application a synthesis of the model compounds (23a and 23b) of Neothramycin (A and B) was described. An efficient chemoselective reduction of the amide was provided.

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