Kinetics and mechanism of methanolysis of benzoyl derivatives of substituted phenylureas and phenylthioureas

J Kaválek, S El Bahaie, V Štěrba

Index: Kavalek, Jaromir; El Bahaie, Said; Sterba, Vojeslav Collection of Czechoslovak Chemical Communications, 1984 , vol. 49, # 9 p. 2103 - 2110

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Abstract

Abstract The methanolysis rate constants and dissociation constants have been measured of benzoyl derivatives of substituted phenylureas and phenylthioureas. The dissociation constants of the thio derivatives are higher by 1 order of magnitude and the rate constants are higher by 2 orders of magnitude than the respective values of the oxygen analogues. Logarithms of the rate and dissociation constants have been correlated with the Hammet σ ...

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