The mechanistic study and synthetic applications of the base treatment in the ozonolytic reactions
YS Hon, SW Lin, L Lu, YJ Chen
Index: Hon, Yung-Son; Lin, Sheng-Wun; Lu, Ling; Chen, Yao-Jung Tetrahedron, 1995 , vol. 51, # 17 p. 5019 - 5034
Full Text: HTML
Citation Number: 66
Abstract
The E1cb mechanism is the overwhelming process in the reaction of bases and ozonides. As a quenching agent in the ozonolysis of a variety of alkenes, the reactions involving triethylamine often gave better yields and proceeded faster than those involving methyl sulfide. On the other hand, in the presence of 4 Å molecular sieves, the secondary amines reacted with mono-and 1, 1-di-substituted ozonides to afford the reductive amination ...
Related Articles:
Effects of $ NaBH_4 $ and laponite on the stability of colloidal Ag nanoparticles
[Alinezhad, Heshmatollah; Tollabian, Zakieh Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 7 p. 1927 - 1930]
[Fujita, Ken-ichi; Enoki, Youichiro; Yamaguchi, Ryohei Tetrahedron, 2008 , vol. 64, # 8 p. 1943 - 1954]
Facile reduction of tertiary lactams to cyclic amines with 9-borabicyclo [3.3. 1] nonane (9-BBN)
[Collins, Christopher J.; Lanz, Marc; Singaram, Bakthan Tetrahedron Letters, 1999 , vol. 40, # 19 p. 3673 - 3676]
[Hajipour; Mallakpour; Najafi Phosphorus, Sulfur and Silicon and Related Elements, 2001 , vol. 170, p. 197 - 203]
[Verardo, Giancarlo; Dolce, Anna; Toniutti, Nicoletta Synthesis, 1999 , # 1 p. 74 - 79]