A new class of bioactivable self-immolative N, O-ligands

…, M Mika, P Miler, R Komor, M Kubicki

Index: Kuznik, Nikodem; Chrobaczynski, Arkadiusz; Mika, Malgorzata; Miler, Patrycja; Komor, Roman; Kubicki, MacIej European Journal of Medicinal Chemistry, 2012 , vol. 52, p. 184 - 192

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Citation Number: 4

Abstract

A hexadentate ligand built on an amine-bis (phenol) skeleton with an aminal, self- immolative moiety is presented. Synthesis of the ligand is convenient and relatively high yielded. Moreover, it enables synthesis of many derivatives, both in the amino-phenol and aminal fragment (various heterocycles). Once the final hexadentate ligand is synthesized via the Katritzky reaction, it becomes prone to hydrolysis. Bioactivation by β-galactosidase ...

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