Journal of fluorine chemistry

The reaction of cyclic β-diketones with trifluoromethylsulphenyl chloride

VI Popov, A Haas, M Lieb

Index: Popov, V.I.; Haas, A.; Lieb, M. Journal of Fluorine Chemistry, 1990 , vol. 47, p. 131 - 136

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Citation Number: 13

Abstract

Abstract The reactions of cyclic β-diketones with trifluoromethylsulphenyl chloride were carried out to give the corresponding CF 3 S-substituted derivatives. Oxidation of the CF 3 S- substituted dimedone led to ring cleavage. The CF 3 SO 2-substituted dimedone was prepared by reaction of trifluoromethylsulphonyl chloride with the metallated β-diketone.

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