Highly Efficient Oxidative Bromination of Alkanes with the HBr??H2O2 System in the Presence of Catalyst
…, J Ju, J Jia, W Sheng, L Han, J Gao
Index: Li, Yujin; Ju, Jie; Jia, Jianhong; Sheng, Weijian; Han, Liang; Gao, Jianrong Chinese Journal of Chemistry, 2010 , vol. 28, # 12 p. 2428 - 2432
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Abstract
Abstract Various cycloalkanes and straight-chain alkanes were efficiently brominated with an aqueous HBr-H 2 O 2 system. This oxidative brominating process was promoted by catalysis and irradiation with light. The cycloalkanes were converted to the corresponding bromo-cycloalkanes in moderate yields and the straight-chain alkanes produced dominantly secondary bromides. This simple but effective bromination method of alkanes is ...
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