1, 5, 7??Triazabicyclo [4.4. 0] dec??1??ene??Mediated Acetylene Dicarboxylation and Alkyne Carboxylation Using Carbon Dioxide

X Wang, YN Lim, C Lee, HY Jang…

Index: Wang, Xi; Lim, Yu Na; Lee, Chan; Jang, Hye-Young; Lee, Bun Yeoul European Journal of Organic Chemistry, 2013 , # 10 p. 1867 - 1871

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Citation Number: 7

Abstract

Abstract Direct carboxylation of acetylene with CO 2 was carried out in the presence of 1, 5, 7-triazabicyclo [4.4. 0] dec-1-ene (TBD); subsequent reduction of dicarboxylated acetylene produces commercially valuable succinate salts. This metal-free carboxylation has potential economic and environmental impact by utilizing non-petroleum feedstocks (acetylene) and CO 2 and by producing valuable chemical feed stocks.

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