Mechanistic investigation of the oxidation of aromatic alkenes by monooxoruthenium (IV). Asymmetric alkene epoxidation by chiral monooxoruthenium (IV) complexes
WH Fung, WY Yu, CM Che
Index: Fung, Wai-Hong; Yu, Wing-Yiu; Che, Chi-Ming Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7715 - 7726
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Citation Number: 84
Abstract
The oxoruthenium (IV) complexes [RuIV (terpy)(6, 6'-Cl2-bpy) O](ClO4) 2 (1a; terpy= 2, 2': 6', 2''-terpyridine; 6, 6'-Cl2-bpy= 6, 6'-dichloro-2, 2'-bipyridine),[RuIV (terpy)(tmeda) O](ClO4) 2 (1b; tmeda= N, N, N', N'-tetramethylethylenediamine),[RuIV (Cn)(bpy) O](ClO4) 2 (1c; Cn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane), and [RuIV (PPz*)(bpy) O](ClO4) 2 (1d; PPz*= 2, 6- bis [(4 S, 7 R)-7, 8, 8-trimethyl-4, 5, 6, 7-tetrahydro-4, 7-methanoindazol-2-yl] pyridine) are ...
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