Intermolecular Mono??and Dihydroamination of Activated Alkenes Using a Recoverable Gold Catalyst
…, C Michon, F Agbossou??Niedercorn
Index: Medina, Florian; Michon, Christophe; Agbossou-Niedercorn, Francine European Journal of Organic Chemistry, 2012 , # 31 p. 6218 - 6227
Full Text: HTML
Citation Number: 13
Abstract
Abstract A combination of gold chloride organometallic complex and a silver salt was used to catalyze intermolecular hydroamination of activated alkenes, ie aza-Michael reactions. The gold-catalyzed reactions of activated alkenes with nitrogen substrates were investigated and found to afford various mono-and dihydroamination products, the latter being rare and original. After flash chromatography, gold NHC catalyst could be recovered as a gold ...
Related Articles:
Nickel-catalyzed dehydrogenation of amines to nitriles
[Yamazaki Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 1 p. 301 - 303]
Configurationally stable propeller-like triarylphosphine and triarylphosphine oxide
[Pinter, Aron; Haberhauer, Gebhard; Hyla-Kryspin, Isabella; Grimme, Stefan Chemical Communications, 2007 , # 36 p. 3711 - 3713]
[Solladie, Guy; Saint Clair, Jean-Francois; Philippe, Michel; Semeria, Didier; Maignan, Jean Tetrahedron Asymmetry, 1996 , vol. 7, # 8 p. 2359 - 2364]
1, 2-Radical rearrangements of aryl, furanyl and thiophenyl groups from carbon to nitrogen
[Journal of the Chemical Society, Chemical Communications, , # 16 p. 1607 - 1608]
Synthesis of homo-and heterobiarylmethylamines
[Synthesis, , # 11 p. 1858 - 1862]