Configurationally stable propeller-like triarylphosphine and triarylphosphine oxide

…, G Haberhauer, I Hyla-Kryspin, S Grimme

Index: Pinter, Aron; Haberhauer, Gebhard; Hyla-Kryspin, Isabella; Grimme, Stefan Chemical Communications, 2007 , # 36 p. 3711 - 3713

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Citation Number: 26

Abstract

Configurationally stable, propeller-like triarylphosphine and triarylphosphine oxide can be synthesized; a chiral scaffold based on Lissoclinum-cyclopeptides linked via three peptide bonds with a triphenylphosphine and triphenylphosphine oxide moiety, respectively, prevents effectively epimerization at the chiral phosphorus atom.