Footprint Catalysis. IV. Structural Effects of Templates on Catalytic Behavior of Imprinted Footprint Cavities.

T Shimada, K Nakanishi, K Morihara

Index: Shimada, Toyoshi; Nakanishi, Kiyoko; Morihara, Kensaku Bulletin of the Chemical Society of Japan, 1992 , vol. 65, # 4 p. 954 - 958

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Citation Number: 29

Abstract

Footprint catalysts are silica (alumina) gel catalysts with tailored specificities. Their catalytic sites are “molecular footprint-like” cavities formed by a molecular imprinting procedure with templates, which are referred to as transition-state or reactive-intermediate analogs of the catalyzed reactions. To clarify the relationship between the structural feature of template molecules and catalytic behavior, seven footprint catalysts were prepared by imprinting ...

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