The Journal of Organic Chemistry

Kinetics and some equilibriums of transacylation between oxy anions in aprotic solvents

IM Kovach

Index: Kovach, Ildiko M. Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2235 - 2241

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Citation Number: 8

Abstract

8-Deuterium isotope effects (@-DIE) determined in acetonitrile for the following reactions are: CH3COO-+ 4NO&&OZCC~(L= H, D)(PNPA-L,), 0.958 0.007 (5-45" C); CHSCOO-+ 2, 4 (NOz) &H30zCCL3 (DNPA-w, 0.964 f 0.011 (5-20" C); OH-+ PNPA-L3, 0.972 f 0.028 (25" C);

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