Rate coefficients for the reactions CH3+ Br2 (224–358 K), CH3CO+ Br2 (228 and 298 K), and Cl+ Br2 (228 and 298 K)

V Khamaganov, JN Crowley

Index: Khamaganov; Crowley International Journal of Chemical Kinetics, 2010 , vol. 42, # 9 p. 575 - 585

Full Text: HTML

Citation Number: 2

Abstract

Abstract Rate coefficients for the reactions of CH 3+ Br 2 (k 2), CH 3 CO+ Br 2 (k 3), and Cl+ Br 2 (k 5) were measured using the laser-pulsed photolysis method combined with detection of the product Br atoms using resonance fluorescence. For the reactions involving organic radicals, the rate coefficients were observed to increase with decreasing temperature and within the temperature range explored, were adequately described by Arrhenius-like ...