A chemoselective route to either 4-methyl-2, 4-diphenyl-2-pentene or 1, 1, 3-trimethyl-3-phenylindane from 2-phenylpropan-2-ol mediated by BiBr 3: a mechanistic …
F Howard, S Sawadjoon, JSM Samec
Index: Howard, Fredrick; Sawadjoon, Supaporn; Samec, Joseph S.M. Tetrahedron Letters, 2010 , vol. 51, # 32 p. 4208 - 4210
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Citation Number: 6
Abstract
Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The reaction of 2-phenylpropan-2-ol mediated by BiBr 3 can, through control of the temperature, yield selectively either 4-methyl-2,4-diphenyl-2-pentene or 1,1,3-trimethyl-3-phenylindane. A reaction mechanism that proceeds via 1-methylstyrene is disclosed. ... The reaction of 2-phenylpropan-2-ol ...
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