Tetrahedron

Cs 2 CO 3 or CaO as promoters of ethyl N-{[(4-methylphenyl) sulphonyl] oxy} carbamate in amination reactions

M Barani, S Fioravanti, L Pellacani, PA Tardella

Index: Barani, Marco; Fioravanti, Stefania; Pellacani, Lucio; Tardella, Paolo A. Tetrahedron, 1994 , vol. 50, # 38 p. 11235 - 11238

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Citation Number: 25

Abstract

Replacing triethylamine by heterogeneous inorganic bases makes it possible to animate benzene or other nitrene acceptors, using the title reagent, previously reported to be scarcely reactive. Products of CH insertion and/or those coming from intermediate aziridines are also obtained.

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