Reaction of lithium alkyls with aldehydes and ketones. General study
JD Buhler
Index: Buhler,J.D. Journal of Organic Chemistry, 1973 , vol. 38, # 5 p. 904 - 906
Full Text: HTML
Citation Number: 47
Abstract
Results The lithium alkyls used were n-butyl-and tert-butyllithium. They were chosen because they are frequently used, they are commercially available, and they represent extreme examples of various lithium reagents (ie,, primary us. tertiary, unhindered vs. sterically hindered). Various typical aldehydes and ketones were used. The reaction products resulting from addition, reduction, and enolization were determined (Chart I). The ...
Related Articles:
[Guijarro, David; Mancheno, Balbino; Yus, Miguel Tetrahedron, 1994 , vol. 50, # 28 p. 8551 - 8558]
THE ACTION OF THE GRIGNARD REAGENT ON HIGHLY BRANCHED CARBONYL COMPOUNDS1
[Conant; Blatt Journal of the American Chemical Society, 1929 , vol. 51, p. 1233]
The Preparation of Some Tertiary Alcohols by the Addition of Organic Acids to Grignard Reagents
[Huston; Bailey Journal of the American Chemical Society, 1946 , vol. 68, p. 1382]
Tertiary Aliphatic Alcohols and Chlorides Containing Normal Butyl Groups
[Whitmore; Woodburn Journal of the American Chemical Society, 1933 , vol. 55, p. 362]
A New Synthesis of Tertiary Hydrocarbons
[Whitmore; Orem Journal of the American Chemical Society, 1938 , vol. 60, p. 2574]