Ni-Catalyzed Cross Coupling of Alkoxide-Containing Vinyl Halides with Grignard Reagents. A “One-Pot” Synthesis of 2-[(Trimethylsilyl) methyl]-2-propen-1-yl Acetate
MG Organ, AP Murray
Index: Organ, Michael G.; Murray, Aaron P. Journal of Organic Chemistry, 1997 , vol. 62, # 5 p. 1523 - 1526
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Citation Number: 27
Abstract
Transition-metal-promoted reactions are extremely useful transformations for many reasons. Perhaps the most useful property of transition-metal complexes is the high degree of selectivity they exhibit in the many different reactions in which they are employed. Late transition metals display a high degree of coordinating affinity for alkene and alkyne moieties. 1 Thus, reactions that involve these groups, such as catalytic hydrogenation2 ...
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