Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid
J Mo, L Xu, J Ruan, S Liu, J Xiao
Index: Mo, Jun; Xu, Lijin; Ruan, Jiwu; Liu, Shifang; Xiao, Jianliang Chemical Communications, 2006 , # 34 p. 3591 - 3593
Full Text: HTML
Citation Number: 33
Abstract
In contrast to almost all of the known examples of Heck arylation of unsaturated alcohols, which yield predominately β-arylated products, arylation under the Pd-DPPP catalysis in ionic liquid leads preferentially to aryl substitution at the α carbon, providing an easy pathway to this valuable class of olefins.
Related Articles:
[Alcaraz, L.; Harnett, J. J.; Mioskowski, C.; Martel, J. P.; Gall, T. Le; et al. Tetrahedron Letters, 1994 , vol. 35, # 30 p. 5449 - 5452]
The influence of intramolecular dynamics on branching ratios in thermal rearrangements
[Newmann-Evans, Richard H.; Simon, Reyna J.; Carpenter, B. K. Journal of Organic Chemistry, 1990 , vol. 55, # 2 p. 695 - 711]
Palladium??Catalyzed Allylic Fluorination
[Hollingworth, Charlotte; Hazari, Amaruka; Hopkinson, Matthew N.; Tredwell, Matthew; Benedetto, Elena; Huiban, Mickael; Gee, Antony D.; Brown, John M.; Gouverneur, Veronique Angewandte Chemie - International Edition, 2011 , vol. 50, # 11 p. 2613 - 2617]
Rhodium promoted isomerisation of allylic alkoxides: a new method for enolate anion formation
[Gazzard, Lewis J.; Motherwell, William B.; Sandham, David A. Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 8 p. 979 - 993]
[Skibbe, Volker; Erker, Gerhard Journal of Organometallic Chemistry, 1983 , vol. 241, # 1 p. 15 - 26]