Die ESR.??Spektren der Radikal??Anionen 1, 6?蟥?berbrückter Cyclodecapentaene

F Gerson, E Heilbronner, WA Böll…

Index: Gerson,F. et al. Helvetica Chimica Acta, 1965 , vol. 48, p. 1494 - 1512

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Citation Number: 41

Abstract

Abstract The ESR.-spectra of the radical anions of 1, 6-methano-cyclodecapentaene (II) and of 1, 6-oxido-cyclodecapentaene (VII), as well as of some of their deutero-derivatives, are reported. The observed spin populations are in essential agreement with the predictions derived from a simple HMO-model, if the electron repelling effect of the bridging groups is included. The reduced width of the spectra may be due to direct leakage of the unpaired ...