Palladium-catalyzed amination of aryl bromides using temperature-controlled microwave heating
Y Wan, M Alterman, A Hallberg
Index: Wan, Yiqian; Alterman, Mathias; Hallberg, Anders Synthesis, 2002 , # 11 p. 1597 - 1600
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Citation Number: 38
Abstract
Abstract Fast Palladium-catalyzed aminations of aryl bromides have been conducted in a non-inert reaction medium with temperature-controlled microwave heating. With a reaction time of 4 minutes at 130 C or 180 C, both electron-rich and electron-deficient aryl bromides reacted with various amines to provide fair to good yields of the corresponding secondary and tertiary anilines. As an example the amination of 4-bromobenzonitrile with imidazole ...
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