Nickel-catalyzed coupling reactions of alkyl electrophiles, including unactivated tertiary halides, to generate carbon–boron bonds
AS Dudnik, GC Fu
Index: Dudnik, Alexander S.; Fu, Gregory C. Journal of the American Chemical Society, 2012 , vol. 134, # 25 p. 10693 - 10697
Full Text: HTML
Citation Number: 87
Abstract
Through the use of a catalyst formed in situ from NiBr2· diglyme and a pybox ligand (both of which are commercially available), we have achieved our first examples of coupling reactions of unactivated tertiary alkyl electrophiles, as well as our first success with nickel- catalyzed couplings that generate bonds other than C–C bonds. Specifically, we have determined that this catalyst accomplishes Miyaura-type borylations of unactivated tertiary, ...
Related Articles:
Rh (I)-catalyzed borylation of primary alkyl chlorides
[Gong, Tian-Jun; Jiang, Yuan-Ye; Fu, Yao Chinese Chemical Letters, 2014 , vol. 25, # 3 p. 397 - 400]
Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation
[Zhang, Lei; Peng, Dongjie; Leng, Xuebing; Huang, Zheng Angewandte Chemie - International Edition, 2013 , vol. 52, # 13 p. 3676 - 3680 Angew. Chem., 2013 , vol. 52, # 13 p. 3676 - 3680,5]
Iridium-catalyzed hydroboration of alkenes with pinacolborane
[Yamamoto, Yasunori; Fujikawa, Rhyou; Umemoto, Tomokazu; Miyaura, Norio Tetrahedron, 2004 , vol. 60, # 47 p. 10695 - 10700]
[Organometallics, , vol. 25, # 25 p. 5965 - 5968]
[Journal of the American Chemical Society, , vol. 129, # 11 p. 3068 - 3069]