The Action of Elementary Fluorine upon Organic Compounds. XX. The Fluorination of Mono-, Di-and Trimethylamine, Ethylenediamine and Ethyleneimine1

JA Gervasi, M Brown, LA Bigelow

Index: Gervasi, J. A.; Brown, M.; Bigelow, L. A. Journal of the American Chemical Society, 1956 , vol. 78, p. 1679 - 1682

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Citation Number: 19

Abstract

This paper describes the direct fluorination under many conditions of a number of different types of aliphatic amines Mono-, di-and trimethylamines underwent not only the expected perfluorination, but also simultaneous dealkylation, alkylation and dimerization such that, for example,(CH&NH gave CF~ NFZ,(CF3) nNF.(CF3) & and (CF&N-N (CF3) 2, together with other products. It was also shown that CHaNHz and (CH3) aN did not evolve NZ during ...