Sulfonylation of organometallic reagents with arenesulfonyl fluorides: a simple one-step synthesis of sulfones
…, EL Sullivan, KP Cusack, JM Funaro
Index: Frye, Leah L.; Sullivan, Eileen L.; Cusack, Kevin P.; Funaro, John M. Journal of Organic Chemistry, 1992 , vol. 57, # 2 p. 697 - 701
Full Text: HTML
Citation Number: 34
Abstract
Sulfonylation of organometallic reagents was accomplished with arenesulfonyl fluorides to provide a wide variety of alkylaryl-and diary1 sulfones. Organolithium and diorganocopper lithium reagents react smoothly with arenesulfonyl fluorides to give sulfones in high yields. Alkyl Grignard reagents often lead to mixtures of monosulfonylated and disulfonylated products. However, allylmagnesium chloride and phenylmagnesium chloride provide the ...
Related Articles:
On the mechanism of the oxidation of tosylhydrazines by N-iodosuccinimide
[Yang, Ding-yah; Han, Oksoo; Liu, Hung-wen Journal of Organic Chemistry, 1989 , vol. 54, # 22 p. 5402 - 5406]
Iron (III) Chloride??Catalyzed Direct Sulfonylation of Alcohols with Sodium Arenesulfinates
[Reddy, M. Amarnath; Reddy, P. Surendra; Sreedhar Advanced Synthesis and Catalysis, 2010 , vol. 352, # 11-12 p. 1861 - 1869]
[Hu, Yi; Chen, Zhen-Chu; Le, Zhang-Gao; Zheng, Qin-Guo Synthetic Communications, 2004 , vol. 34, # 21 p. 4031 - 4035]
[Knipe,A.C.; Stirling,C.J.M. Journal of the Chemical Society [Section] B: Physical Organic, 1967 , p. 808 - 814]