Synthesis of bis (trifluoromethyl) trisulfide and bis (trifluoromethylthio) selenide
…, DI Rossman, DK Rohrbaugh, CP Ferguson
Index: Munavalli, S.; Muller, A. J.; Rossman, D. I.; Rohrbaugh, D. K.; Ferguson C. P. Journal of Fluorine Chemistry, 1994 , vol. 67, # 1 p. 37 - 40
Full Text: HTML
Citation Number: 9
Abstract
Abstract The use of 4-dimethylaminopyridine as a catalyst in the reaction of trifluoromethylsulfenyl chloride with hydrogen sulfide at− 78 C cuts down the time of reaction from 30 d to 1 d and gives up to 70% yield of bis (trifluoromethyl) trisulfide (1). Similarly, bis (trifluoromethylthio) selenide (2) can be prepared from hydrogen selenide and trifluoromethylsulfenyl chloride. The influence of other catalysts on the course of the ...
Related Articles:
The Synthesis and Chemistry of Fluoroazoalkanes
[Chambers,W.J. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 2337 - 2343]
Fluorothiocarbonyl Compounds. 1 I. Preparation of Thio Ketones, Thioacyl Halides, and Thio Esters
[Middleton,W.J. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 1375 - 1384]
The Reactions of Uranium Hexafluoride with Hydrogen Sulfide and with Carbon Disulfide
[Trevarrow, L. E.; Fischer, J.; Gunther, W. H. Inorganic Chemistry, 1963 , vol. 2, p. 1281 - 1284]
Some chemistry of fluorinated octahedral sulfur compounds
[Kitazume,T.; Shreeve,J.M. Journal of the American Chemical Society, 1978 , vol. 100, p. 492 - 496]
Some chemistry of fluorinated octahedral sulfur compounds
[Kitazume,T.; Shreeve,J.M. Journal of the American Chemical Society, 1978 , vol. 100, p. 492 - 496]