Synthesis and reactions of" anhydrochloralurethanes"

H Ulrich, B Tucker, AAR Sayigh

Index: Ulrich,H. et al. Journal of Organic Chemistry, 1968 , vol. 33, p. 2887 - 2889

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Citation Number: 27

Abstract

The previously unreported anhydrochloralurethans (I) are obtained by dehydrochlorination of alkyl 1, 2, 2, 2-tetrachloroethylcarbamates (111). Reaction of I with water, alcohols, and amines affords chloral 0, N-and N, N-acetals. The latter compounds are also produced in the reaction of chloralurethana (11) with alkyl and aryl isocyanates. Treatment of I1 and I11 with carbonyl chloride in the presence of N, N-dimethylformamide aa the catalyst gives rise to ...