Journal of the American Chemical Society

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh (III) Catalyst in the C–H Activation and Oxygen Atom …

RB Dateer, S Chang

Index: Li, Bin; Park, Yoonsu; Chang, Sukbok Journal of the American Chemical Society, 2014 , vol. 136, # 3 p. 1125 - 1131

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Citation Number: 43

Abstract

The first example of Rh (III)-catalyzed cyclization of arylnitrones to indolines under external oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal alkynes is made possible by the dual role of the Cp* Rh (III) catalyst mediating both the C–H

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