Site-selective mono-oxidative addition of active zinc into carbon–bromine bond of dibrominated-thiophenes: preparation of thienylzinc reagents and their applications
HS Jung, HH Cho, SH Kim
Index: Jung, Hye-Soo; Cho, Hyun-Hee; Kim, Seung-Hoi Tetrahedron Letters, 2013 , vol. 54, # 8 p. 960 - 964
Full Text: HTML
Citation Number: 4
Abstract
A facile protocol for the preparation of 3-bromo-2-thienylzinc bromide A and 5-bromo-2- thienylzinc bromide B has been developed. It has been successfully accomplished by a site- selective oxidative addition of active zinc into a chemically pseudo-equivalent or equivalent
Related Articles:
[Abdelsamie, Ahmed S.; Bey, Emmanuel; Hanke, Nina; Empting, Martin; Hartmann, Rolf W.; Frotscher, Martin European Journal of Medicinal Chemistry, 2014 , vol. 82, p. 394 - 406]
Polymer-supported syntheses of thiophene-containing compounds using a new type of traceless linker
[Ben-Haida, Abderrazak; Hodge, Philip Organic and Biomolecular Chemistry, 2012 , vol. 10, # 9 p. 1754 - 1763]