Photochemical Beckmann rearrangements. Correspondence between substituent effects in oximes and oxaziridines
Y Ogata, K Takagi, K Mizuno
Index: Ogata, Yoshiro; Tagaki, Katsuhiko; Mizuno, Kiyohiko Journal of Organic Chemistry, 1982 , vol. 47, p. 3684 - 3687
Full Text: HTML
Citation Number: 18
Abstract
he relative migratory tendencies of hydrogen and aryl groups in the photochemical Beckmann rearrangement of benzaldoximes 2a-c were compared with those in the photochemical rearrangement of 2-aky1-3-aryloxaziridines 3a-f. The migratory tendencies depended on the nature of the aryl substituent and were similar in 2a-c and 3a-q implying that the photochemical Beckmann rearrangement proceeds through an oxaziridine ...
Related Articles:
Photochemical and thermal reactions of 2-aryloxybenzohydroxamic acids
[Das, Vijay Kumar; Devi, Rashmi Rekha; Thakur, Ashim Jyoti Applied Catalysis A: General, 2013 , vol. 456, p. 118 - 125]
Electrochemical synthesis of amides: direct transformation of methyl ketones with formamides
[Huang, Haolai; Yuan, Gaoqing; Li, Xianwei; Jiang, Huanfeng Tetrahedron Letters, 2013 , vol. 54, # 52 p. 7156 - 7159]
[Zhang, Nana; Li, Binyao; Zhong, Hongban; Huang, Jianhui Organic and Biomolecular Chemistry, 2012 , vol. 10, # 47 p. 9429 - 9439]
[Friestad, Gregory K.; Ji, An Organic Letters, 2008 , vol. 10, # 11 p. 2311 - 2313]
[Friestad, Gregory K.; Ji, An Organic Letters, 2008 , vol. 10, # 11 p. 2311 - 2313]