Catalyst??Controlled Wacker??Type Oxidation of Protected Allylic Amines
…, JR McCombs, A Winkler, MS Sigman
Index: Michel, Brian W.; McCombs, Jessica R.; Winkler, Andrea; Sigman, Matthew S. Angewandte Chemie - International Edition, 2010 , vol. 49, # 40 p. 7312 - 7315
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Citation Number: 42
Abstract
The Tsuji–Wacker oxidation provides access to methyl ketones from terminal olefins and is commonly utilized in complex molecule synthesis.[1] However, this reaction is under substrate control, which can lead to a mixture of aldehyde and ketone products, especially when the alkene bears a proximal heteroatom.[2, 3] An excellent example of exploiting this was recently reported by Feringa and co-workers wherein allylic phthalimides provided ...
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