Microwave-assisted Negishi and Kumada cross-coupling reactions of aryl chlorides
P Walla, CO Kappe
Index: Walla, Peter; Kappe, C. Oliver Chemical Communications, 2004 , # 5 p. 564 - 565
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Citation Number: 67
Abstract
The biaryl motif is found in a range of pharmaceuticals, natural products, agrochemicals, ligands, conducting polymers, liquid crystals and advanced materials. 1 The Negishi cross-coupling reaction utilizing organozinc reagents represents a powerful method for the synthesis of this privileged structural scaffold. 2 One major disadvantage of Pd or Ni-catalyzed Negishi couplings is the rather long reaction times involving hours or even days. Recent evidence suggests ...
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