A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br 3 CCOOEt/PdCl 2 as the catalyst
P Srithanakit, W Chavasiri
Index: Srithanakit, Phatsupha; Chavasiri, Warinthorn Tetrahedron Letters, 2011 , vol. 52, # 19 p. 2505 - 2507
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Citation Number: 5
Abstract
Abstract Bromosilanes were prepared conveniently and efficiently via the reaction of hydrosilanes and Br 3 CCOOEt in the presence of a catalytic amount of PdCl 2 in refluxing THF over 15 min in high yields. The developed methodology was further applied for the one- pot synthesis of silyl ethers and silyl esters in excellent yields.
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