Direct fluorination of secondary nitronate salts

K Baum

Index: Baum,K. Journal of Organic Chemistry, 1970 , vol. 35, p. 846 - 849

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Citation Number: 13

Abstract

NOz Since 2-nitro alcohols and 2-nitro acids readily undergo deformylation and decarboxylation, respectively, the fluoro derivatives could be expected to serve as convenient precursors to 1-fluoro-1-nitro alkanes. One must bear in mind, however, that a fluorines have been shown to decrease the acidity of substituted nitro methaneslg and this destabilization of nitronate salts would also tend to inhibit the deformylation and ...