The Direction of Addition of Carbon Tetrachloride to CFCl= CF2 under Polar Conditions1

AL Henne, DW Kraus

Index: Henne; Kraus Journal of the American Chemical Society, 1951 , vol. 73, p. 5303

Full Text: HTML

Citation Number: 8

Abstract

Dissociation constants of some of the saturated aliphatic dicarboxylic acids from four carbon atoms to fourteen carbon atoms have been determined at 25.0'in 20 wt. per cent. methanol- water solution by the method of Speakman. These experimental results and also the available constants for water as solvent are analyzed in terms of the theory of Kirkwood and Westheimer. It is found that the theory gives quite satisfactory agreement with the ...