Effect of the Michael Acceptor in the asymmetric intramolecular Stetter reaction
MS Kerr, T Rovis
Index: Kerr, Mark S.; Rovis, Tomislav Synlett, 2003 , # 12 p. 1934 - 1936
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Citation Number: 19
Abstract
Abstract The effect of different Michael acceptors was evaluated in the catalytic asymmetric intramolecular Stetter reaction. Utilizing a readily prepared chiral triazolium salt as a nucleophilic carbene precursor, the reactivity and selectivity of substrates containing different electron-deficient double bonds was shown to vary significantly under identical reaction conditions.
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