One??pot synthesis of polyrotaxane by clipping and cyclopolymerization of α, ω??diethynyl isophthalamide with pyridiniumdicarboxamide chloride

T Isono, T Satoh, T Kakuchi

Index: Isono, Takuya; Satoh, Toshifumi; Kakuchi, Toyoji Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 14 p. 3184 - 3192

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Citation Number: 7

Abstract

Abstract The one-pot synthesis of a main chain-type polyrotaxane composed of axle molecules threaded through the macrocyclic units on the polymer main chain was achieved via the combination of cyclopolymerization and clipping procedures. The cyclopolymerization of an α, ω-diethynyl monomer bearing an isophthalamide moiety (1), which clips onto an axle component bearing a pyridiniumdicarboxamide moiety (2· Cl) ...

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