Polystyrene and polymethacrylate resin-supported Jacobsen's alkene epoxidation catalyst

L Canali, E Cowan, H Deleuze, CL Gibson…

Index: Canali, Laetitia; Cowan, Elaine; Deleuze, Herve; Gibson, Colin L.; Sherrington, David C. Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 13 p. 2055 - 2066

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Citation Number: 126

Abstract

Polystyrene and polymethacrylate-based resin supported Jacobsen's chiral Mn salen complexes have been prepared. The resins are of defined molecular structure and morphology, and the complexes have been attached primarily in a pendant fashion. The loadings of Mn (III) are in the range≈ 0.08–0.35 mmol g− 1 to maximise the likelihood of site- isolation. The polymer-supported complexes have been used as enantioselective ...